Bis(μ-2-carboxy-5-nitrobenzoato-κ2 O 1:O 1)bis[(2,2′-bipyridine-κ2 N:N′)chloridocopper(II)] dihydrate
نویسنده
چکیده
The asymmetric unit of the title complex, [Cu(2)(C(8)H(4)NO(6))(2)Cl(2)(C(10)H(8)N(2))(2)]·2H(2)O, contains two half binuclear complex molecules and two solvent water molecules; the complete complex molecule is generated by the application of a centre of inversion in each case. Each independent Cu(II) cation is penta-coordinated within a distorted square-pyramidal environment defined by a two μ(2)-O atoms (derived from two 2-carboxy-5-nitrobenzoato anions), two N atoms (bipyridine ligand) and one Cl. Binuclear species are assembled into a two-dimensional supramolecular architecture parallel to (01[Formula: see text]) by O-H⋯O and O-H⋯Cl hydrogen bonds.
منابع مشابه
[μ-2,2′-(1,4-Phenylene)diacetato-κ2 O 1:O 4]bis[aqua(2,2′-bipyridine-κ2 N,N′)chloridocopper(II)] dihydrate
In the centrosymmetric title compound, [Cu(2)(C(10)H(8)O(4))Cl(2)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, the Cu(II) atom is five-coordinated in a distorted square-pyramidal geometry by two N atoms from a chelating 2,2'-bipyridine ligand, one O atom from a 1,4-phenyl-enediacetate ligand, one Cl atom and one water mol-ecule. The 1,4-phenyl-enediacetate ligand, lying on an inversion center, bridges ...
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